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In effect, we can find independent modes of oscillation of When we say we are differentiating at constant the solid [1,2]. Didier Ebo. Journal of Physics and Chemistry of Solids Thermal expansion and kinetic coefficients of crystals. There are two different coordination environments for the Zn atoms, namely Zn1 and Zn2, both having tetrahedral geometry. We report here the solvothermal synthesis and crystal structure of a three-dimentional zinc II -based metal�organic framework solid, [Zn 3 H 2 O 2 btc 2 4,4'-bipy ] n , I.